Determination of polydimethylsiloxane using heat capacity change in a glass transition region.
نویسندگان
چکیده
منابع مشابه
Heat capacity at the glass transition
A fundamental problem of glass transition is to provide a quantitative and microscopic explanation of the heat-capacity jump at the glass transition temperature Tg . Similar problems are also common to other disordered systems, including spin glasses. We propose that the jump of heat capacity at Tg takes place as a result of the change of the liquid’s elastic, vibrational, and thermal propertie...
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The heat capacity of a supercooled liquid subjected to a temperature cycle through its glass transition is studied within a kinetic model. In this model, the beta process is assumed to be thermally activated and described by a two-level system. The alpha process is described as a beta relaxation mediated cooperative transition in a double well. The overshoot of the heat capacity during the heat...
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15 صفحه اولLow-temperature excess heat capacity in fresnoite glass and crystal
The effect of thermal annealing on low-temperature excess heat capacity was investigated in fresnoite (Ba2TiSi2O8) glass. The amplitudes of the excess heat capacity decreased, and their positions shifted to a higher temperature by relaxation or crystallization. In particular, we revealed that the change in the excess heat capacity during transition from the glassy state to the crystalline state...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1989
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.38.3_115